1 拼音
Meerwein-Ponndorf fǎn yìng
醛或酮与异丙醇铝在异丙醇溶液中加热,还原成相应的醇,而异丙醇则氧化为丙酮,将生成的丙酮由平衡物中慢慢蒸出来,使反应朝产物方向进行。这个反应相当于Oppenauer氧化的逆向反应。
2 反应机理
3 反应实例
4 参考文献
[1] H. Meerwein and R. Schmidt, Ann. 444, 221 (1925).
[2] W. Ponndorf, Angew. Chem. 39, 138 (1926).
[3] A. Verley, Bull. Soc. Chim. France [4] 37, 537, 871 (1925).
[4] A. L. Wilds in Organic Reactions II, 178 (1944).
[5] T. Bersin, in Newer Merhods of Preparative Organic Chemistry, English Ed. (Interscience, NewYork, 1948), p 125.
[6] L. M Jackson and J. A. Mills, Nature 164, 789 (1949).
[7] V. N. Moulton, R. E. Van Atta, and R. R. Ruch, J. Org. Chem. 26, 290 (1961).
[8] V. J Shiner and D. Whittaker, J. Amer. Chem. Soc. 85, 2337 (1963).
[9] B. J. Yager and C. K. Hancock, J. Org. Chem. 30, 1174 (1965).
参见:Oppenauer氧化